Before arriving in Venice, Pitt added professional photographer to his ever-expanding resumé. He snapped Jolie for the November cover of W, PEOPLE has confirmed.
The photo shoot, first reported by Fashion Week Daily, took place at Chateau Miraval in Provence, France, where the Pitt-Jolies have been since Jolie gave birth July 12 to twins Knox Léon and Vivienne Marcheline.
Source : People

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